I run 30lb braid on my PST ... with a 3ft leader of 6lb test mono. But, I'm using baitcast reels. If your spinning reels are capable of handling the braid & have the capacity to hold the length of line needed ... I see no reason why they wouldn't work just fine.
Just be sure to use some mono backing on the reels, then finish filling the spool with the braid. That'll stop the braid from spinning on the arbor (under pressure) due to the "no stretch & slickness" of braid.